Unlock superior fuel quality control with advanced PIONA analysis

The analysis of hydrocarbon content Paraffins, Iso-paraffins, Olefins, Naphthenes, and Aromatics (PIONA) is essential for ensuring the quality and performance of automotive spark-ignition engine fuels. Traditional methods such as ASTM D6839 often require multiple traps and complex configurations, making the analysis more time-consuming and complicated.

ApplicationAnalyzing petroleum-based fuel on PIONA
Measuring Object Liquid SampleLiquid Sample
Targeted ComponentsGasoline and refinery streams
Reference MethodASTM D8071
VUVVersusGasChromatographic1
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Advantages of GC-VUV Solution

  1. Shorter Runtime: VUV detection allows for faster analysis.
  2. Versatility: GC-VUV can analyze a wide range of compounds, including hydrocarbons and oxygenates, in a single run.
  3. Deconvolution of Co-Eluting Compounds: The VUV detector’s unique spectral fingerprints enable the separation and identification of overlapping compounds, improving accuracy.
  4. Detailed Spectral Information: GC-VUV provides both qualitative and quantitative data, offering a more comprehensive analysis of the sample composition.

Below is a comparison of VUV with other techniques.

Other GC TechniqueVUV Technique
Range: Gasoline, Naphtha up to C12Range: Gasoline, Naphtha up to C14
Multiple ColumnsOne column
Multiple rotary valvesNo Valves
FID detectorVUV detector
S/SL injection portS/SL Injection port
Group separationIndividual or group type reporting
Multiple adsorption trapsNo Adsorption traps
N2 carrier gasHelium (Hydrogen & N2 possible)
Selectivity of traps; 5 carbon numbersNo limit to selectivity of carbon numbers
Other processing softwareVUV software (VUV Analyze)
OpenLab softwareOpenLab software or without
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VUV Versus Other Gas Chromatographic Methods

The analysis of hydrocarbon content Paraffins, Iso-paraffins, Olefins, Naphthenes, and Aromatics (PIONA) is essential for ensuring the quality and performance of automotive spark-ignition engine fuels. Traditional methods such as ASTM D6839 often require multiple traps and complex configurations, making the analysis more time-consuming and complicated.

With the Vacuum Ultraviolet (VUV) Detector, PIONA analysis becomes significantly simpler and more efficient, offering several advantages:

Simplified Configuration – No need for multiple traps or complex plumbing
Enhanced Compound Identification – Unique spectral signatures enable reliable differentiation of hydrocarbon classes
Improved Data Quality – Accurate quantification of PIONA components
Faster Analysis – Reduced method complexity leads to shorter analysis time
Greater Flexibility – Capable of analyzing complex fuel matrices with high confidence

By leveraging VUV detection technology, laboratories can streamline gasoline characterization while maintaining high analytical accuracy and reliability.

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